# Oils and Determining The Viscosity Temperature Dependence Of Engine Oils With Equipment From Malvern Instruments

## Topics Covered

Background

Temperature Dependent Viscosity

Mineral Oils

Viscostatic Oils

Effect Of Viscosity Variations

Interpretation Of Viscosity Versus Temperature

Conclusion

Measurement Conditions

## Background

Engine oils and lubricants need to provide a good layer thickness by having sufficient viscosity, without giving significant frictional effects from the viscosity being too high. The ideal viscosity range of an engine oil is therefore quite narrow.

## Mineral Oils

Mineral oils generally have a very temperature dependent viscosity and so need to be modified.

## Viscostatic Oils

Viscostatic oils (where viscosity is entirely independent of temperature) can be created by adding polymeric compounds that open up their conformation at higher temperatures. When heated, the increase of viscosity of the polymer additive counteracts the fall in viscosity of the oil.

## Effect Of Viscosity Variations

In this experiment, we can measure the viscosity of the oil at all working temperatures and determine whether it will be sufficiently ‘thin’ when cold, for say, an engine to start, or sufficiently ‘thick’ to lubricate well when hot.

## Interpretation Of Viscosity Versus Temperature

The results show that Sample A’s low temperature viscosity is much higher than that of Sample B and therefore it will be much more difficult to circulate in an engine on start-up. Conversely, Sample B showed a higher viscosity than Sample A when hot, indicating that it would give more lubrication when up to temperature.

 Figure 1. Variation in viscosity over a range of temperatures.

## Conclusion

The temperature dependence of a lubricant is one of the most important factors in determining its efficacy. Using a Bohlin rheometer, the viscosity can be accurately measured over a wide temperature range. Results are also referenced against nationally recognised standards.

## Measurement Conditions

 Samples Oils and lubricants Geometry Parallel Plate 40 mm with the Extended Temperature Cell Single Shear – Shear Rate 10s-1 Gap 1 mm Temperature Ramp Range of interest (eg.-20ºC – 90ºC at 3º/min)

Source: Petrochemicals Application Note by Malvern Instruments.