Indium Tin Oxide - Materials, Applications and Development of ITO in Touch Screen Technology by NanoMarkets

Topics Covered

Background
Touch-Screen Technology Market Overview
Material Selection for Touch-Screen Display
Resistive Touch Technology
Capacitive Touch Technology
Alternative Touch Screen Technology
PEDOT Formulation
Carbon Nanotubes for Touch Screens
Other ITO-based Formulations
Future Market of ITO

Background

NanoMarkets is a leading provider of market and technology research and industry analysis services for the thin film, organic and printable electronics businesses (which we refer to as TOP Electronics.) Since the firm founding, NanoMarkets has published over two dozen comprehensive research reports on emerging technology markets. Topics covered have included sensors, displays, OLEDs, HB-LEDs, e-paper, RFID, photovoltaics, smart packaging, novel battery technologies, printed electronics, organic electronics, emerging memory and storage technologies and other promising technologies. Our client roster is a who who of companies in specialty chemicals, materials, electronics applications and manufacturing. NanoMarkets also hosts a blog at www.nanotopblog.com where we discuss technology trends, company announcements and the industry on-going progress.

Touch-Screen Technology Market Overview

Touch-screen technology, already widespread in applications ranging from PDAs to checkout displays, has become even more popular since the introduction of novel consumer electronics such as Apple's iPhone and follow-on clones. According to a report published by NanoMarkets, The Future of ITO: Transparent Conductor and ITO Replacement Markets, March 2008, as much as $118 million in transparent conductor will be sold into the touch-screen market in 2008, rising to $400 million by 2015.

Material Selection for Touch-Screen Display

Transparent conductors combine the electrical conductivity of metal with the optical transparency of glass. They are the ideal material for touch screens, since they make for nearly invisible electrical traces. The dominant transparent conductor is indium tin oxide (ITO), which is found in nearly every touch screen on the market today. Unfortunately, it's the optical electronics version of a shampoo-conditioner: While it possesses both properties, it doesn't perform either one to optimal standards.

In addition, while demand for indium keeps increasing, sources for it are limited, leading to fears of rising prices and short supply. Given the proportionate amount of ITO in touch screens, higher indium prices could have a significant impact on total materials costs. Those concerns have led the Indium Corporation to put a disclaimer on its Web site reassuring customers of continued supply at reasonable prices.

More critically, ITO is brittle, and often cracks from overuse, yet touch screens are now employed in a wide variety of medical devices. For example, the state of the art surgical suites at UCLA's newly opened Ronald Reagan Medical Center feature touch screens that allow surgeons to adjust viewing angles for laparoscopic surgical tools. In such a situation, the stakes for a cracked ITO rise from merely annoying to possibly life-threatening.

Given all of that, touch screens are the most tempting target ITO replacement solutions.

Resistive Touch Technology

The two primary touch-screen technologies in the marketplace are "resistive touch" and "capacitive touch." Resistive touch screens, about 90 percent of the current market, have two ITO layers that must be pressed together to make electrical contact, which then activates a controller. The screen interface is a protective outer layer onto which pressure is ideally applied with a soft stylus. Unfortunately, under real world conditions, pressure is often applied with pens or sharp fingernails, shortening the life of many resistive touch displays. But even when pressed only by a stylus, they often crack after repeated flexing.

By contrast, capacitive touch screens, employed in devices like the iPhone, are activated by lightly brushing a finger on the screen, eliminating the possibility of cracking (providing the device isn't dropped). In this way, they use the body's own conductance to shift the stored electrical charge (capacitance) of the device. When the screen is touched by a finger or hand, an ITO substrate detects the change in the capacitive field, which activates the controller.

Capacitive Touch Technology

Capacitive touch is often called "multi-touch," since several fingers or even full hands can be used to direct the devices. New terms may emerge as more trademarked devices are developed. Microsoft, for example, has a tabletop capacitive touch screen it calls "Microsoft Surface." Depending on the sophistication of the underlying programming, capacitive touch also allows for much more fluid navigation than "press here" resistive screens, such as the iPhone's ability to "zoom in." In the next few years, capacitive screens will make serious in-roads into sales of resistive touch screens.

Due to their tendency to crack, resistive touch screens are the leading edge of the ITO replacement market. In addition, since ITO is used as part of the flat panel display in all touch screens, as well as the electrical control, it would be advantageous to have a ready supply of an alternative material.

Alternative Touch Screen Technology

There are four areas in which the alternatives compete: price, conductivity, transparency, and resiliency. Although several alternatives score well in two or three areas, none have yet scored on all four. More challenging, many are still in the development phase.

Other transparent conducting oxides (TCOs) might seem a good place to start, since they often cost less than ITO, while possessing its favorable characteristics (transparency, conduction). Unfortunately, they share its worst one as well: They tend to crack under repeated use. If researchers improve the electrical conduction of alternate TCOs, they may find a home in some applications, but they would not be an improvement for touch screens.

Of the potential ITO replacements, perhaps the best known is the conducting polymer PEDOT Poly(3,4-ethylenedioxythiophene), which has already been used by Fujitsu to build touch screens. The good news is that it is both more flexible and far cheaper than ITO, at only about ten percent of its price. The bad news is that conductive polymers are less conductive than metals. Nevertheless, doping and other laboratory strategies can be used to improve their conductivity. But even with improved chemistry, PEDOT can degrade under UV light.

PEDOT Formulation

H.C. Starck markets a proprietary formulation (PEDOT:PSS) under the tradename "Baytron," which is a compound of PEDOT with polystyrene sulfonic acid. Starck says its latest version has conductivities that equal some metal oxides. But, at conductivities of up to 500 C/cm, it is still an order of magnitude less conductive than ITO (6000 C/cm). PEDOT:PSS is a likely leading contender in the replacement market because it is highly transparent and thermally stable in comparison to other polymers. In addition, the potential is there to tweak the formula to further increase its conductivity without degrading its transparency.

Carbon Nanotubes for Touch Screens

Despite hope for a new kind of electronics based on carbon nanotubes (CNTs), so far they are still more in the research phase than the application phase. If they advance, they have several advantages for touch screens. They are highly conductive and flexible, and would be relatively transparent at the necessary densitiesaking for good, potential ITO replacements. Companies such as Eikos and Unidym are pouring a lot of resources into developing commercial carbon nanotubes, but nothing yet exists that would transform the touch-screen market. Unidym is working on a CNT-based conductive film, which it plans to market as an ITO replacement in touch screens and other displays. The company plans to jointly develop touch screens for the video game industry with Japanese manufacturer Touch Panel Laboratories. However, in the immediate future, carbon nanotubes likely will be most often used for electrostatic coatings, according to Eikos.

While there are other nanomaterials that are not specifically nanotubes, none have made it to the marketplace. Companies doing research in this area include Sony, DuPont, and Cambrios, co-founded by MIT professor and MacArthur Award winner Angela Belcher. Still, this area leaves room for optimismoth carbon nanotubes and other nanomaterials are the only areas where truly novel, market-changing technical breakthroughs could occur. One example is the metallic nanowire arrays developed by the lab of L. Jay Guo at the University of Michigan. They are ductile, flexible, and conductive; their mesh-like structure gives them transparency. Guo is now considering researching their potential use in touch screens.

Other ITO-based Formulations

These are not replacements, per se, but re-workings of traditional ITO manufacturing processes, such as ITO nanopowders and ITO inks. Most are still in the research phase, and while they may eventually offer flexible solutions to fabrication, they have not overcome ITO's traditional problems.

Future Market of ITO

ITO is likely to dominate the touch-screen market for the foreseeable future. Nevertheless, since there are good reasons to find a replacement, NanoMarkets predicts that by 2015, ITO will only be 44.8 percent of the market. By 2015, we believe the top three replacements in order of market penetration will be: organics (PEDOT) at 18 percent; carbon nanotube-based formulations at 15 percent; and other nanomaterials at 9 percent.

Source: "The Future of ITO: Transparent Conductor and ITO Replacement Markets", Market Report by Nanomarkets

For more information on this source please visit NanoMarkets

Date Added: Dec 23, 2008 | Updated: Jun 11, 2013
Ask A Question

Do you have a question you'd like to ask regarding this article?

Leave your feedback
Submit