Understanding and Controlling the Moisture and Ash Content of Biomass Fuel

Biomass is a form of renewable energy obtained from live organic materials or materials that were recently alive. Alcohol fuels, black liquor, refuse, corn husks and wood pellets are typical examples of materials that are categorized as biomass.

Like fossil fuels, these materials are incinerated to generate energy, but are more sustainable. To optimize the fuel efficiency of biomass, it is essential to understand and control the moisture and ash content of the biomass. Moreover, incomplete combustion can produce black carbon, which is a pollutant.

The moisture content of biomass materials is typically determined with a conventional oven and ash content with a furnace. Although these traditional techniques are reliable, they often take a long time, which make manufacturers incapable of addressing problems arising during processing.

The development of a new approach for moisture and ash analysis enables accurate moisture and ash determination. This method uses an instrument that provides results in real time, correlating final water and ash concentrations to standard test procedures currently utilized for multiple materials in various industries. The significant reduction in analysis time allows manufacturers to make necessary process changes rapidly in order to achieve optimum output.

Moisture and Ash Analysis

Moisture and ash analysis was performed on a device utilizing the linked testing option, which allows performing a moisture test and subsequent ash test devoid of any user input or interface. Testing parameters were set up before testing and in-situ monitoring was performed. Preconditioning of waffle pans before analysis was done to avoid film formation.

For each test, the sample was uniformly distributed on the sample pan. The testing conditions may vary for different materials in order to optimize results, and it may not be possible to use the idle temperature because the ash analysis begins immediately after the moisture analysis.

Based on the testing criteria, the user may use the sample mass taken before the moisture analysis or after the moisture analysis if the moisture content is not required in the determination of ash content. The pan tare is not desired because the pan mass remains unchanged after being removed at the beginning of the moisture analysis.

Analysis Results

The mean results for the moisture analysis of the biomass material samples are summarized in Table 1, showing a strong agreement between the oven reference and the MAX® 5000XL and the repeatability of the MAX® 5000XL. However, there is a significant difference in analysis times between the two techniques.

Table 1. Moisture results for biomass materials.

Testing Conditions Moisture Test Ash Test
Idle Temperature 50°C 125°C
Test Temperature 125°C 600°C
Ending Criteria 0.5000%/minute 0.0500%/minute
Sample Size 7g +/- 1g 7g +/- 1g
Pan Tare Standard Standard
Sample Tare 5 seconds 5 seconds

The ash results for the same biomass materials are summarized in Table 2, showing the strong correlation and repeatability between these analysis techniques, but with a significant difference in analysis times. It should also be noted that the analysis times given in Table 2 for the reference method represent the time when the sample is at the given test temperature and do not include the time needed for the furnace to achieve the test temperature and the time taken by the crucibles to cool down to room temperature. Conversely, the analysis times shown for the MAX® 5000XL represent the averaged analysis times taken for each biomass material to complete the entire analysis.

Table 2. Ash results for biomass materials.

Material MAX® 5000XL Reference
Wood Pellet 25 minutes Test Time 1 hour
1.3293 % Ash 1.397
0.1021 S.D. 0.1305
Pecan Shell 35 minutes Test Time 2 hours
2.1294 % Ash 2.2734
0.2437 S.D. 0.0944
Wood Chip 40 minutes Test Time 2 hours
0.5575 % Ash 0.5373
0.0463 S.D. 0.0582
Wood Pellet with Pecan Bagger 30 minutes Test Time 2 hours
3.7175 % Ash 4.5263
0.3465 S.D. 1.283

Figures 1 and 2 depict the test graphs showing the progress of moisture and ash analysis in real time using the Computrac® MAX® 5000XL. It is possible to adjust the test criteria based on the characteristics of the graph. This, in turn, enables changing the criteria to optimize the analysis time if it is desired.

Test graph for moisture analysis of wood pellets.

Figure 1. Test graph for moisture analysis of wood pellets.

Test graph for ash analysis of wood pellets.

Figure 2. Test graph for ash analysis of wood pellets.

Conclusion

Rapid loss-on-drying and ash content analyzers are essential for manufacturers of biomass materials as they significant reduce analysis times when compared to conventional testing methods.

This capability of rapid loss-on-drying and ash content analyzers enables manufacturers to achieve improved productivity and market-reach time. Further, these devices save money by removing testing variables, improving employee output, and lowering energy costs.

About Arizona Instrument

Initially known as the Quintel Corporation, Arizona Instrument LLC was founded in 1981 by a group of engineers breaking away from The Motorola Corporation who were dedicated to the idea of providing precision moisture analysis instruments that were accurate, reliable, and easy to use.

The first instrument released was the MA Moisture Analyzer, but the company quickly expanded its Computrac® moisture analysis line and became an accepted leader in moisture analysis, setting a standard that has been adopted by many Fortune 500 companies.

Today the Computrac® line is comprised of three technologies: rapid loss-on-drying, high temperature loss-on-ignition, and moisture specific analysis using polymer capacitance sensor, GREEN alternative to Karl Fischer.

Arizona Instrument

This information has been sourced, reviewed and adapted from materials provided by Arizona Instrument.

For more information on this source, please visit Arizona Instrument.

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