Band Excitiation Technique provides Insight into Unique Properties of Materials

The revolutionary new Band Excitation (BE) technique, co-developed by Oak Ridge National Laboratory (ORNL) and Asylum Research, has provided clues to the origins of unique properties of materials including spin and cluster glasses, phase-separated oxides, polycrystalline ferroelectrics, and ferromagnets, that are rooted in their highly disordered structures.

Spatial maps of non-linearity for different film thicknesses (thicknesses shown across top). The onset of nonlinearity with thickness proceeds through formation and merger of clearly visible micron-scale clusters with bulk nonlinearity value, as opposed to gradual increase of average nonlinearity.

These behaviors influence the scaling properties of the materials, including the thickness of thin films at which improved properties manifest. So-called "Rayleigh behaviors" have a direct bearing on the properties of nanoscale materials and, eventually, the uniformity of nanoscale devices. The new observations, which were made possible by advances in scanning probe microscopy (SPM) at ORNL's Center for Nanophase Materials Sciences and Asylum Research, may result in the rethinking of 100-year-old theories behind the "quanta of nonlinearity" and properties of heterogeneous materials.

This work is funded by the Department of Energy's Basic Energy Sciences CNMS user program. The principal investigators for this ground-breaking work are Stephen Jesse and Sergei Kalinin of ORNL, and Susan Trolier-McKinstry from Penn State. The findings were recently published in Proceedings of the National Academy of Sciences (PNAS), April 20, 2010 entitled "Collective dynamics underpins Rayleigh behavior in disordered polycrystalline ferroelectrics."

Sergei Kalinin of ORNL commented, "The nonlinear responses are a ubiquitous aspect of disordered materials that is directly linked to their unique functional properties. Our studies illustrate that the emergence of the nonlinear behavior is associated with large-scale collective responses, providing new clues to century-old problems."

Added Roger Proksch, President of Asylum Research, "The amazing aspect of BE measurements is that the local nonlinearity is measured quantitatively with less than 10% absolute error in volumes millions of times smaller than those addressable by macroscopic measurements. This is highly unusual for SPM."

Citations

Please use one of the following formats to cite this article in your essay, paper or report:

  • APA

    Asylum Research - An Oxford Instruments Company. (2019, February 10). Band Excitiation Technique provides Insight into Unique Properties of Materials. AZoM. Retrieved on September 15, 2019 from https://www.azom.com/news.aspx?newsID=21533.

  • MLA

    Asylum Research - An Oxford Instruments Company. "Band Excitiation Technique provides Insight into Unique Properties of Materials". AZoM. 15 September 2019. <https://www.azom.com/news.aspx?newsID=21533>.

  • Chicago

    Asylum Research - An Oxford Instruments Company. "Band Excitiation Technique provides Insight into Unique Properties of Materials". AZoM. https://www.azom.com/news.aspx?newsID=21533. (accessed September 15, 2019).

  • Harvard

    Asylum Research - An Oxford Instruments Company. 2019. Band Excitiation Technique provides Insight into Unique Properties of Materials. AZoM, viewed 15 September 2019, https://www.azom.com/news.aspx?newsID=21533.

Tell Us What You Think

Do you have a review, update or anything you would like to add to this news story?

Leave your feedback
Submit