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Supplier Data – Arsenic (As) (Goodfellow)

Supplier Data – Arsenic (As) (Goodfellow)

Chemical Formula

As

Topics Covered

Background

Occurrence

Production

Applications

Key Properties

Background

Discovered in the 13th. century by Albertus Magnus (although believed to have been used much earlier as an alloying addition to bronze to provide a lustrous finish).

Arsenic is found in several allotropic forms and has both metallic and non-metallic properties. The grey metallic allotrope is a brittle, crystalline solid which tarnishes readily in air and burns in oxygen. It is resistant to attack by dilute acids and alkalis, but will react with hot acids and molten NaOH.

Occurrence

Arsenic is poisonous (it is thought to have been responsible for the death of Napoleon) and occurs both free and combined in many minerals (Arsenic has an abundance within the earth's crust of 1.5 ppm).

Production

The non-metallic allotropes include yellow arsenic (may be formed by rapid condensation of Arsenic vapour in an inert atmosphere) and black arsenic (may be formed by slow condensation of the vapour in an inert atmosphere).

Applications

Applications for grey arsenic include its use as an alloying element, its use in the manufacture of certain types of glass and as a donor impurity in germanium semiconductor devices.

Key Properties

Atomic Properties

 

Atomic number

33

Atomic radius - Goldschmidt ( nm )

0.125

Atomic weight ( amu )

74.9216

Crystal structure

Rhombohedral

Electronic structure

Ar 3d10 4s2 4p3

Photo-electric work function ( eV )

5.1

Thermal neutron absorption cross-section ( Barns )

4.3

Valences shown

-3, 0, 3, 5

Ionisation Potential

No.

eV

 

1

9.81

 

2

18.6

 

3

28.4

 

4

50.1

 

5

62.6

 

6

128

Natural Isotope Distribution

Mass No.

%

 

75

100

Electrical Properties

 

Electrical resistivity @20°C ( µOhm.cm )

33.3

Mechanical Properties

 

Material condition

Polycrystalline

Bulk modulus ( GPa )

22.0

Hardness - Vickers

57-69

Physical Properties

 

Boiling point (°C )

616

Density @20°C ( g.cm-3 )

5.73

Melting point (°C )

Sublimes >300

Thermal Properties

 

Coefficient of thermal expansion @0-100°C ( x10-6 K-1 )

5.6

Latent heat of fusion ( J.g-1 )

370

Specific heat @25°C ( J.K-1.kg-1 )

328

Thermal conductivity @0-100°C ( W.m-1.K-1 )

50.2

 

Date Added: Feb 11, 2003


 

 

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