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Supplier Data – Osmium (Os) (Goodfellow)

Supplier Data – Osmium (Os) (Goodfellow)

Chemical Formula

Os

Topics Covered

Background

Abundance and Occurence

Extraction

Applications

Key Properties

Background

Osmium was discovered in 1803 by Smithson Tennant in London, England.

Pure osmium is silver in colour and is the densest of all metals. It has a pungent smell, due to the formation of osmium tetroxide

Abundance and Occurrence

Osmium is a member of the platinum group of metals and is commonly found in conjunction with these elements (abundancy is 1 x 10-4 ppm in the earth’s crust).

Extraction

The mixed metals can be extracted from the ore with aqua regia, followed by treatment of the soluble and insoluble portions in various ways. Osmium is found in both portions and is removed as the volatile tetroxide, which can then be reduced.

Applications

Applications for osmium include its use as an alloying constituent with other group metals, the resultant alloys being extremely hard (e.g. osmiridium, a naturally occurring alloy of osmium and iridium which is extremely hard and is used for the tips of pen nibs). Osmium can also be used as a powerful catalyst in gas reactions.

Key Properties

Atomic Properties

 

 

 

Atomic number

76

Atomic radius - Goldschmidt ( nm )

0.135

Atomic weight ( amu )

190.2

Crystal structure

Hexagonal close packed

Electronic structure

Xe 4f14 5d6 6s2

Photo-electric work function ( eV )

4.8

Thermal neutron absorption cross-section ( Barns )

15.3

Valences shown

0, 1, 2, 3, 4, 5, 6, 7, 8

Ionisation Potential

No.

eV

 

 

1

8.7

 

 

2

16

 

Natural Isotope Distribution

Mass No.

%

 

 

184

0.02

 

 

186

1.58

 

 

187

1.6

 

 

188

13.3

 

 

189

16.1

 

 

190

26.4

 

 

192

41.0

 

Electrical Properties

 

 

 

Electrical resistivity @20°C ( µOhm.cm )

8.8

Temperature coefficient @0-100°C ( K-1 )

0.0041

Superconductivity critical temperature ( K )

0.66

Mechanical Properties

 

 

 

Material condition

Soft

Hard

Polycrystalline

Bulk modulus ( GPa )

 

 

373

Hardness - Vickers

300-350

670-1000

 

Poisson’s ratio

 

 

0.25

Tensile modulus ( GPa )

 

 

559

Physical Properties

 

 

 

Boiling point (°C )

5027

Density @20°C ( g.cm-3 )

22.5

Melting point (°C )

3045

Thermal Properties

 

 

 

Coefficient of thermal expansion @0-100°C ( x10-6 K-1 )

4.57

Latent heat of evaporation ( J.g-1 )

3305

Latent heat of fusion ( J.g-1 )

154

Specific heat @25°C ( J.K-1.kg-1 )

131

Thermal conductivity @0-100°C ( W.m-1.K-1 )

87.6

 

Date Added: Feb 11, 2003


 

 

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