In this interview AZoM talks to Christine Desplat, Technical Support Team Member at Master Bond Inc., about structural adhesives and how they handle extreme heat.
What stresses typically affect a bond joint in different applications?
Lap shear stress is one of the most common stresses that a bonded joint faces during service, especially in structural bonding applications. The lap shear strength of an adhesive serves not only as a good gauge for an adhesive’s structural strength profile, but it is also an indicator for a bonded joint’s long term sustenance in an application context.
How is lap shear tested?
The industry standard for measuring lap shear strength for adhesives is the ASTM D-1002, wherein aluminum coupons are bonded together in a lap joint with an adhesive applied between the substrates and cured. The parts are then sheared at incremental loads in the tensile mode, and therefore referred to as tensile lap shear.
What test protocol did Master Bond develop for validating long term resistance to high temperatures?
In order to further test the long term sustenance in an application context, Master Bond simulated an environment in which bonded lap joints were subjected to high temperatures for long periods of time. The experiment involved performing a before and after (exposure to high temperatures) lap shear strength measurement. The lap shear was tested for aluminum to aluminum. Metal coupons roughly measuring 4” x 1” x 1/16” were roughened and cleaned with acetone, prior to adhesive application. These metal substrates were bonded together and the adhesive cured according to the recommended cure schedule. They were then subjected to 500 hours of exposure to 300°F (~ 150°C). Resistance to elevated temperatures is a critical factor for many aerospace, electronics, and oil & gas applications, where high temperature resistance is generally considered as a good indicator of performance under harsh environments.
What products were chosen for this test?
Adhesives EP17HTDA-1, Supreme 12AOHT-LO, FLM36, and Supreme 10HT were selected considering their relatively high Tg and good lap shear strength at room temperature. EP17HTDA-1, Supreme 12AOHT-LO, and Supreme 10HT were cured at 250°F (125°C) for 2 hours followed by 300°F (150°C) for 5 hours. The cure schedule for FLM36 was 300°F (150°C) for 4 hours followed by 350°F (175°C) for another 4 hours.
The bonded samples were then tested after 500 hours of exposure to 300°F (150°C).
How well did these products work?
Five bonded samples of Master Bond systems EP17HTDA-1, Supreme 12AOHT-LO, FLM36, and Supreme 10HT were tested and compared to a standard two component epoxy that cures at room temperature. The results in the graph below display the lap shear strength of these adhesive systems before and after heat exposure. They also are average values along with error bars indicating a narrow standard of deviation between readings.
The outcomes show that the four systems were not significantly affected despite exposure to aggressive temperature conditions. Although EP17HTDA-1 had the biggest loss in lap shear strength, the lap shear strength value after this high temperature condition was still pretty high. FLM36 and Supreme 12AOHT-LO displayed the highest lap shear strength for bonding similar substrates after prolonged exposure to high temperatures, with the Supreme 10HT not too far behind. All four adhesives displayed much higher lap shear strength than a typical two component room temperature curing epoxy.
How do these adhesives perform when bonding dissimilar substrates under the same test protocol?
In a second experiment, lap shear strength is tested for aluminum to stainless steel bonding, before and after prolonged heat exposure. The substrates were prepared and cured as noted above for the aluminum to aluminum bonding.
Again, results show that the four systems were not significantly affected despite exposure to aggressive temperature conditions. Here, FLM36 and Supreme 12AOHT-LO displayed the highest lap shear strength retention for bonding dissimilar substrates.
To summarize, these products have demonstrated their ability to maintain excellent mechanical strength properties, even after prolonged exposure to elevated temperatures. It is also important to note that heat curing or post heat curing epoxy adhesives will significantly improve their temperature resistance and strength properties.
About Christine Desplat
Christine Desplat is an R&D Engineer at Master Bond where she analyzes application oriented issues and provides product solutions for companies in the aerospace, electronics, medical, optical, and oil/chemical industries. She received a Bachelor's Degree in Chemical Engineering from Rensselaer Polytechnic Institute.
Disclaimer: The views expressed here are those of the interviewee and do not necessarily represent the views of AZoM.com Limited T/A AZoNetwork the owner and operator of this website. This disclaimer forms part of the Terms and conditions of use of this website.