Copper (II) Oxide Semiconductors

Topics Covered

Description
Applications
Chemical Properties
Electrical Properties
Thermal, Mechanical and Optical Properties
Safety Information

Description

Copper (II) oxide is a higher oxide of copper and belongs to the monoclinic crystal system. It occurs as a black solid with an ionic structure that melts above 1200°C with some loss of oxygen. It is an irritant, and causes damage to the central nervous system and endocrine system. It can be formed by heating copper in air.

Applications

Copper (II) oxide finds applications in the following:

  • It is used as pigment in ceramics and fungicide
  • It is rarely used as a dietary supplement in animals
  • It has application as a p-type semiconductor due to its narrow band gap
  • It is used to produce dry cell batteries/wet cell batteries
  • It is used as an alternative for iron oxide in thermite.

Chemical Properties

The chemical properties of copper (II) oxide are provided in the table below:

Chemical Properties
Chemical Formula CuO
Molecular Weight 79.545
CAS No. 1317-38-0
Group Copper – 11
Oxygen - 16
Crystal Structure Monoclinic
Lattice Constant a = 4.684 Å
b = 3.425 Å
c = 5.129 Å

Electrical Properties

The electrical properties of copper (II) oxide are provided in the table below:

Electrical Properties
Magnetic Susceptibility 0.000238
Band Gap 1.2 eV

Thermal, Mechanical and Optical Properties

The thermal, mechanical and optical properties of copper (II) oxide are provided in the tables below:

Thermal Properties
Heat of Fusion 148.3 J/g
Heat of Formation -156 kJ/mol
Specific Heat Capacity 42.3 J/mol K
Mechanical Properties
Density 6.315 g/cm3
Melting Point 1326°C
Boiling Point 2000°C
Optical Properties
Refractive Index 2.63

Safety Information

Safety Information
GHS Hazard Statements H302 - Harmful if swallowed
H410 - Very toxic to aquatic life with long lasting effects.
Safety Precautions P273: Avoid release to the environment.

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