The researchers will present their findings today at the American Chemical Society (ACS) Spring 2019 National Meeting & Exposition. ACS, the world’s largest scientific society, is holding the meeting here through Thursday. It features nearly 13,000 presentations on a wide range of science topics.
Paramagnets are materials that are weakly attracted to a magnetic field and are not permanently magnetized. But by adding alloys, paramagnets have been transformed into ferromagnets, or regular permanent magnets, like the metal surface of a refrigerator. Lograsso’s team at the Critical Materials Institute at Ames Laboratory has identified two promising candidates thus far using this “rehabilitative” approach, and both are forms of cerium cobalt: CeCo3 and CeCo5. Although cerium is called a rare-earth element, it is very abundant and easy to obtain.
Previous work on CeCo3 showed that it exhibited classic paramagnetic behavior. Calculations predicted that by adding magnesium, paramagnetic CeCo3 could be transformed into a ferromagnet. These predictions have been experimentally validated, Lograsso says, and this property has been observed in measurements of single crystals of the compound.
CeCo5 is a strong ferromagnet. The researchers combined theoretical calculations with high-throughput experiments to zero in on the exact amount of copper and iron to add that would optimize the compound’s ferromagnetism. With these additives, the team anticipates that CeCo5 could someday be used in place of the strongest rare-earth magnets that contain neodymium (Nd) and dysprosium (Dy), thus easing demand for those critical elements. Lograsso and colleagues continue to investigate other similar metals that can be added to CeCo5 to further improve its suitability as a viable substitute for Nd and Dy magnets.
“Replacing rare-earth magnets, which are in high demand, would be ideal, both economically and environmentally,” Lograsso says. “Although our modified cerium-cobalt compounds are not as powerful as rare-earth magnets, they could still be highly valuable for certain commercial applications. So, our goal is to match the right magnet material to a specific application — a so-called ‘Goldilocks’ non-rare-earth magnet.”
To that end, the group continues to use their strategy to optimize the key characteristics of poor magnets or non-magnets to transform them into alternatives that are completely free of rare-earth elements. For example, they are now using cobalt to optimize the performance of iron germanium, Fe3Ge. The resulting compound’s high magnetization is comparable with the best Nd-based magnets. This strategy is not just limited to Fe3Ge and is being applied to other promising rare-earth-free compounds to selectively improve magnet properties.
The researchers acknowledge support and funding from the U.S. Department of Energy.
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