New Scientific Instrument Reveals Liquid-Like Properties of Perovskites

Scientists at McGill University have acquired stimulating new knowledge about the properties of perovskites, one of the world’s most sought after materials for developing a more efficient, stronger, and economical solar cell.

(Image credit: McGill University)

In a research work reported recently in Nature Communications, the scientists used a multi-dimensional electronic spectrometer (MDES)—an exclusive instrument hand-built at McGill University—to monitor the behavior of electrons in cesium lead iodide perovskite nanocrystals.

The MDES that enabled these observations has the ability to measure the behavior of electrons across extremely short time frames—down to 10 femtoseconds, or ten-millionths of a billionth of a second. Perovskites are apparently solid crystals that first gained attention in 2014 for their unique potential to be used in future solar cells that might be cheaper or more fault-tolerant.

A Most Exciting Discovery

It’s the most exciting result that I have been a part of since starting in science in 1995,” stated senior author and McGill chemistry professor Patanjali Kambhampati, reporting about the discovery of a unique feature of perovskites—liquid-solid duality. “Instead of searching for perfection in defect-free silicon microelectronics, here we have a defective thing that’s defect-tolerant. And now we know a bit more about why that is.”

Solids Acting Like Liquids

With the close examination of the crystals using the MDES, the scientists observed something that challenged their traditional understanding of the difference between solids and liquids.

Since childhood, we have learned to discern solids from liquids based on intuition: we know solids have a fixed shape, whereas liquids take the shape of their container. But when we look at what the electrons in this material are actually doing in response to light, we see that they behave like they typically do in a liquid. Clearly, they are not in a liquid —they are in a crystal—but their response to light is really liquid-like.

Hélène Seiler, Study Lead Author, Department of Physical Chemistry, Fritz-Haber-Institut, Max-Planck Institute

Seiler continued, “The main difference between a solid and a liquid is that a liquid has atoms or molecules dancing about, whereas a solid has the atoms or molecules is more fixed in space as on a grid.”

Seiler was a former PhD student in the Department of Chemistry at McGill University.

The study received funding from Natural Sciences and Engineering Research Council of Canada (NSREC), Canada Foundation for Innovation (CFI), Swiss National Science Foundation, and Fonds de Recherche du Québec—Nature et technologies (FQRNT).

Source: https://www.mcgill.ca

Citations

Please use one of the following formats to cite this article in your essay, paper or report:

  • APA

    Ali, Sabina. (2019, November 06). New Scientific Instrument Reveals Liquid-Like Properties of Perovskites. AZoM. Retrieved on November 12, 2019 from https://www.azom.com/news.aspx?newsID=52399.

  • MLA

    Ali, Sabina. "New Scientific Instrument Reveals Liquid-Like Properties of Perovskites". AZoM. 12 November 2019. <https://www.azom.com/news.aspx?newsID=52399>.

  • Chicago

    Ali, Sabina. "New Scientific Instrument Reveals Liquid-Like Properties of Perovskites". AZoM. https://www.azom.com/news.aspx?newsID=52399. (accessed November 12, 2019).

  • Harvard

    Ali, Sabina. 2019. New Scientific Instrument Reveals Liquid-Like Properties of Perovskites. AZoM, viewed 12 November 2019, https://www.azom.com/news.aspx?newsID=52399.

Tell Us What You Think

Do you have a review, update or anything you would like to add to this news story?

Leave your feedback
Submit